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 Magnetic Resonance in Chemistry and Medicine by Ray Freeman, X Magnetic resonance (MR) measures the tiny radio frequency signals emitted by the nucleus of the atom when living or inanimate material is placed in a magnetic field. On the one hand, these signals allow scientists to picture the architecture of molecules too small to be seen under the most powerful microscope, while on the other hand they give medical doctors a detailed picture of the internal structure of the human body without resorting to surgery of any kind. These two applications (high-resolution NMR spectroscopy and the MRI scanner) seem to be worlds apart, but the underlying physical principles are the same, and it makes sense to treat them together. Chemists and clinicians who use magnetic resonance have much to learn about each other's specialities if they are to make the best use of magnetic resonance technology. Many in the medical fraternity will benefit from a general appreciation of how high-resolution NMR has advanced our understanding of human biochemistry, diagnostic medicine, and the search for new drugs. A broad general understanding of magnetic resonance should prove of interest to doctors who make use of the MRI scanner, and to those of their patients who wish to learn more about these daunting machines, even if it is only the question of their own personal safety. At the other end of the spectrum, chemists and biochemists who use high-resolution NMR spectroscopy in their everyday investigations will benefit by broadening their horizons to cover the exciting new developments in MR imaging and in vivo spectroscopy, as one justification for their research is the eventual benefit to health care. Finally, anyone interested in how the human mind works (cognitiveneuroscience) will find a chapter devoted to the exciting new developments in functional magnetic resonance imaging of the brain. Each disparate group has something useful to learn from the others. The treatment is pictorial rather than mathematical.
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Continuous phase-frequency-shift keying - Continuous phase-frequency-shift keying (CPFSK) is a commonly-used variation of frequency-shift keying (FSK), which is itself a special case of analog frequency modulation. FSK is a method of modulating digital data onto a sinusoidal carrier wave, encoding the information present in the data to variations in the carrier's instantaneous frequency between one of two frequencies (referred to as the space frequency and mark frequency). Frequency reference - A frequency reference is an instrument used for providing a stable frequency of some kind. There are different sorts of frequency references, acoustic ones such as tuning forks but also electrical ones that emit a signal of a certain frequency (a frequency standard). Center frequency - The center frequency f0 (resonant frequency) is the geometric mean between the lower cutoff frequency f1 and the upper cutoff frequency f2 of a frequency band. See also: Band-pass filter. Beat frequency oscillator - A beat frequency oscillator or BFO in radio telegraphy, is a dedicated oscillator used to create an audio frequency signal for carrier wave transmissions to make them audible, as they are not broadcast as such. The signal from the BFO is then heterodyned with the intermediate frequency signal to create an audio frequency signal.
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